Reducing carbon dioxide (CO2) into valuable chemicals is a key strategy for mitigating climate change and achieving carbon neutrality. Traditional catalysts face challenges in selectivity and efficiency. Based on these issues, it is crucial to explore new strategies to improve the performance of electrocatalysts. Due to these challenges, an in-depth study is needed to advance the field.
A team from The Hong Kong Polytechnic University, led by Bolong Huang, published a review (DOI: 10.1016/j.esci.2023.100140) on 11 May 2023, in eScience, investigating the neighboring effects in single-atom catalysts for CO2 reduction. The study highlights the importance of surrounding atoms in modulating the electronic properties of single-atom catalysts (SACs), thereby enhancing their catalytic performance.
The review summarizes various neighboring effects and their influence on the electrochemical reduction of CO2. SACs, known for their catalytic activity, benefit from the electronic modulation induced by neighboring atoms. These atoms can act as additional active sites, facilitating electron transfer and improving CO2 reduction efficiency. The study also explores the coordination effect on single metal active sites and presents an outlook for examining neighboring effects in other electrocatalytic processes. Both theoretical and experimental evidence suggests that neighboring sites enhance SAC performance by providing secondary active locations during the catalytic process.
Dr. Bolong Huang, the lead researcher, stated, "Our findings on neighboring effects open new avenues for designing advanced single-atom catalysts. By understanding how neighboring atoms influence the catalytic process, we can develop more efficient and sustainable solutions for CO2 reduction."
This research provides valuable insights into the design of advanced SACs for efficient electrocatalysis. The improved understanding of neighboring effects could lead to the development of better catalysts for sustainable energy conversion, ultimately contributing to efforts in combating climate change and achieving carbon neutrality.
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References
DOI
10.1016/j.esci.2023.100140
Original Source URL
https://doi.org/10.1016/j.esci.2023.100140
Funding information
The authors gratefully acknowledge the support from the National Natural Science Foundation of China Grant Council of Hong Kong Joint Research Scheme (N_PolyU502/21), the funding for Projects of Strategic Importance of The Hong Kong Polytechnic University (Project Code: 1-ZE2V), Shenzhen Fundamental Research Scheme-General Program (JCYJ20220531090807017), the Natural Science Foundation of Guangdong Province (2023A1515012219) and Departmental General Research Fund (Project Code: ZVUL) from Department of Applied Biology and Chemical Technology of Hong Kong Polytechnic University.
About eScience
eScience is an open access journal publishing the latest scientific and technological research emerging from interdisciplinary fields related to energy, electrochemistry, electronics and the environment. It focuses on delivering critical insights and highlighting innovation. Original, important or general interest contributions covering a diverse range of topics are considered.